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Sintez I Khimicheskie Svoystva Karboranov : Dikarbaundekaboraty, metallo- i metallakarborany, azometiny, slozhnye efiry, peroksidy, soli karborankarbonovykh kislot
Bok av Rudakov Dmitriy Aleksandrovich
V monografii rassmotreny khimicheskie svoystva o-karborana i 7,8-dikarba-nido-undekaborata sistematizirovannye po tipam khimicheskikh reaktsiy, privodyatsya kak sobstvennye dannye avtorov za period raboty v Institute fiziko-organicheskoy khimii NAN Belarusi, tak i dannye drugikh avtorov. Privoditcya ryad novykh dannykh po sintezu galogen- i poligalogenproizvodnykh o-karborana i 7,8-dikarba-nido-undekaborata ranee ne opublikovannykh v literature. Na primere galogenproizvodnykh karborana vpervye otmecheno dezaktiviruyushchee i aktiviruyushchee vliyanie zamestiteley na reaktsii elektrofil'nogo zameshcheniya. Stroenie sintezirovannykh soedineniy podtverzhdeno dannymi elementnogo analiza i metodami UF, IK, YaMR 1N, 11V i 11V-11V COSY spektroskopii. Monografiya perednaznachena spetsialistam, rabotayushchim v oblasti sozdaniya preparatov dlya tseley bor-neytronozakhvatnoy terapii raka, pererabotki vysokoaktivnykh otkhodov atomnoy energetiki po UNEX-tekhnologii, sozdaniya lekarstvennykh preparatov novogo pokoleniya na osnove zameny dvumernoy aromatiki na trekhmernuyu, a takzhe khimikam organikam spetsializiruyushchimsya na reaktsiyakh kross-sochetaniya i spektroskopii YaMR 11V. Monografiya soderzhit 109 tablits, 83 risunka, bibliografiya 860.