Novye Organilkhal'kogenidy, Soderzhashchie Azot, Fosfor, Kremniy, Germaniy : Razrabotka metodov sinteza novykh funktsional'nykh organicheskikh khal'kogenidov

V knige predstavleny rezul'taty sistematicheskikh issledovaniy po razrabotke novykh metodov sinteza ranee neizvestnykh ili trudnodostupnykh lineynykh i tsiklicheskikh funktsionalizirovannykh organicheskikh khal'kogenidov. Razrabotany effektivnye sposoby polucheniya organilkhal'kogenilalkilfosfonatov i ikh pervichnykh alkilfosfinov. Opisannye v dannoy rabote ranee neizvestnye pervichnye organilkhal'kogenilalkilaminy i ikh gidrokhloridnye soli byli bazovymi soedineniyami v sinteze sera-, selen- i tellursoderzhashchikh osnovaniy Shiffa. Ikh palladievye kompleksy effektivny v reaktsiyakh kross-sochetaniya v aerobnykh usloviyakh. Izucheny novye reaktsii prisoedineniya-tsiklizatsii digalogenidov, tetragalogenidov selena i tetrakhlorida tellura k dietinilsilanam(germanu), privodyashchie k pervym predstavitelyam novykh klassov: selenasila(germa)ful'venam, selenasila(germa)tsiklopentenam i tellurasilaful'venam. Stroenie soedineniy dokazano s pomoshch'yu YaMR spektroskopii, mass-spektrometrii, IK spektroskopii, RSA, GZhKh. V rabote ispol'zovany kvantovo-khimicheskie raschety dlya issledovaniya mekhanizmov reaktsiy.